Synthesis, Electrochemical and Electrochromic properties of Novel Aromatic Polymers Bearing Pendent Triphenylamine Groups

新型具三苯胺側鏈基團之芳香族高分子之合成與電化學及電致變色性質之研究

期刊論文：

(1) S. H. Cheng, S. H. Hsiao, T. H. Su, G. S. Liou* “Novel Aromatic Poly(amine-imide)s Bearing a Pendent Triphenylamine Group: Synthesis, Thermal, Photophysical, Electrochemical, and Electrochromic Characteristics” Macromolecules 2005, 38, 307 (2012 SCI IF: 5.521)

(2) G. S. Liou*, S. H. Hsiao, T. H. Su “Synthesis, Luminescence and Electrochromism of Aromatic Poly(amine-amide)s with Pendent Triphenylamine Moieties” J. Mater. Chem. 2005, 15, 1812. (2012 SCI IF: 6.101)

(3) T. H. Su, S. H. Hsiao, G. S. Liou* “Novel Family of Triphenylamine-containing, Hole-transporting, Amorphous, Aromatic Polyamides with Stable Electrochromic Properties” J. Polym. Sci. Part A: Polym. Chem. 2005, 43, 2085 (2012 SCI IF: 3.543)

(4) G. S. Liou*, T. H. Su, S. H. Hsiao “Novel Thermally Stable  Poly(amine-hydrazide)s and Poly(amine-1,3,4-oxadiazole)s for Luminescent and Electrochromic Material” J. Polym. Sci. Part A: Polym. Chem. 2005, 43, 3245  (2012 SCI IF: 3.543)

(5) S. H. Cheng, S. H. Hsiao, T. H. Su, G. S. Liou* “Novel Electrochromic Aromatic Poly(amine-amide-imide)s with Pendent Triphenylamine Structures” Polymer 2005, 46, 5939. (2012 SCI IF: 3.379)

(6) K. Y. Chiu, T. H. Su, C. W. Huang, G. S. Liou, S. H. Cheng “Substituent Effects on the Electrochemical and Spectral Characteristics of N,N,N',N'-Tetraaryl-p-Phenylenediamine Derivatives" J. Electroanalytical Chemistry. 2005, 578, 283. (2012 SCI IF: 2.672)

(7) K. Y. Chiu, T. H. Su, J. H. Li, T. H. Lin, G. S. Liou, S. H. Cheng* “Novel Trends of Electrochemical Oxidation of Amino-substituted Triphenylamine Derivatives” J. Electroanalytical Chemistry. 2005, 575, 95 (2012 SCI IF: 2.672)
　

研討會論文：

　　Poster Presentation

　　(1) 邱國源,蘇賜祥,鄭淑華,劉貴生,蘇玉龍,

　　　“p-phenylenediamine 之電化學及光譜電化學研究”

　　　2003, 中國化學會Presented at the Annual Meeting of R.O.C Chemistry Symposium. Taoyuan, Taiwan. Nov, (2003).　

　　(2) T. H. Su, K. Y. Chiu, G. S. Liou, S. H. Cheng, Y. Oliver. Su,

　　　“Synthesis of small organic hole-transport molecules based on the triphenylamine unit”

　　　Presented at the Annual Meeting of R.O.C Chemistry Symposium. Taoyuan, Taiwan. Nov, (2003).

　　(3) K. Y. Chiu, T. H. Su, S. H. Cheng, G. S. Liou, Y. Oliver. Su,

　　　“Electrochemical characterization of small organic hole-transport molecules based on the tetraaryl-p-phenylenediamines”,

　　　International Chemical Conference, Taipei; Analytical Chemistry, Oct. 30, (2003).

　　(4) S. H. Cheng, K. Y. Chiu, T. H. Su, G. S. Liou, S. M. Wang, C. W. Huang

　　　“The 206th Meeting of The Electrochemical Society” Oct. 3, (2004). Honolulu, Hawaii.

　　(5) G. S. Liou, T. S. Su, S. H. Hsiao,

　　　“Synthesis, Luminescence, and Electrochromism of Aromatic Poly(amine-amide)s With Pendent Triphenylamine Moieties”

　　　Presented at the European Polymer Congress 2005. June 30, Moscow, Russia. P.137 (2005).

                                                    高分子材料受到UV光的照射放出不同顏色的光。              高分子材料的電化學性質。

高分子材料的電致變色性質。左圖為此高分子材料的第一個變色波段，隨著電位的增加從原本的顏色變成綠色。

                      右圖為此高分子材料的第二個變色波段，隨著電位的增加從綠色變成深藍色。